Volume 139
Main Index

Issues 1-2, Pages 1-354 (1 December 1987)

Foreword Pages xi-xii K. W. Bagnall

Preface Page xv K. W. Bagnall, J. Marçalo, A. Pires de Matos

Lanthanides since 1839: From crowded elements to quantum-chemical Rosetta Stone Pages 1-5 Christian K. Jørgensen

Concepts and techniques in the discovery of the actinide elements Pages 7-12 A. G. Maddock

Some aspects of the coordination and organometallic chemistry of thorium and uranium (MIII, MIV, UV) in +3 and +4 oxidation states Pages 13-20 Paul C. Blake, Michael F. Lappert, Richard G. Taylor, Jerry L. Atwood and, Hongming Zhang

New trends in the structural chemistry of actinide and lanthanide coordination compounds Pages 21-32 Gabriella Bombieri

Europium(III) complexation reactions in water Pages 33-38 Herbert B. Silber

Schiff base complexes of lanthanides and actinides Pages 39-48 P. A. Vigato, D. E. Fenton

Crystal structures of three UO22+ complexes with S-donors Pages 49-50 Mark Pennington, Nathaniel W. Alcock, David Brown

Crystal structure of the adduct of thorium(IV) tetrakisacetylacetonate with aniline, [Th(C5H7O2)4]2·C6H5NH2 Pages 51-53 P. J. Reeves, A. J. Smith

A novel (3 + 3) hexaimine Schiff base macrocyclic complex of lanthanum Pages 55-57 D. E. Fenton, S. J. Kitchen, C. M. Spencer, P. A. Vigato and, S. Tamburini

Lanthanide complexes with macrocyclic and macroacyclic Schiff bases Pages 59-60 E. Bullita, U. Casellato, P. Guerriero, P. A. Vigato

Actinide complexes with Schiff bases: the first crystal structure of a binuclear thorium(IV) complex with a pentadentate compartmental ligand Pages 61-63 U. Casellato, P. Guerriero, S. Tamburini, P. A. Vigato, R. Graziani

Dioxouranium(VI) complexes with polydentate Schiff bases containing acetal groups Pages 65-66 S. Sitran, D. Fregona, U. Casellato, P. A. Vigato, G. Faraglia

Lanthanide complexes with pyridine-2,6-dicarboxylic and thiophene-2,5-dicarboxylic acids Pages 67-68 P. Guerriero, U. Casellato, S. Sitran, P. A. Vigato, R. Graziani

Novel Schiff base complexes of some f-transition and related elements Pages 69-70 Hassan A. Tayim

Polypyrazolylborate complexes of yttrium and lanthanum Pages 71-73 Daniel L. Reger, Jeffrey A. Lindeman, Lukasz Lebioda

Mixed pyrazolylborate-β-diketonate-Ln(III) complexes Pages 75-78 Wayne D. Moffat, Matthew V. R. Stainer, Josef Takats

Synthesis and characterization of UCl2[HB(3,5-Me2pz)3](3,5-Me2pz) and MCl3[HB(3,5-Me2pz)3](3,5-Me2pzH) (M=U(IV) and Th(IV); PZ=pyrazolyl) Pages 79-81 Noémia Marques, J. Marçalo, A. Pires De Matos, K. W. Bagnall, J. Takats

U(IV) and Th(IV) hydrotris(3,5-dimethylpyrazolyl)borate complexes with asymmetric metal centres Pages 83-85 Noémia Marques, J. Marçalo, Teresa Almeida, J. M. Carretas, A. Pires de Matos, K. W. Bagnall, J. Takats

Reduction of uranium(IV) complexes containing the hydrotris(3,5-dimethylpyrazolyl)borate ligand Pages 87-88 Isabel Santos, Noémia Marques, A. Pires de Matos

Uranium(IV) bishydrotris(pyrazol-1-yl)boratothiolato derivatives Pages 89-90 Isabel Santos, Noémia Marques, A. Pires de Matos

Preparation and crystal structures of tetrakis(methyltrihydroborato)uranium(IV)bis(tetrahydrofuranate) and tetrakis(methyltrihydroborato)uranium(IV)tetrahydrothiophenate Pages 91-95 Ron Shinomoto, Allan Zalkin, Norman M. Edelstein

Preparation of some Lewis base adducts of tris(methyltrihydroborato)Ho and Yb and crystal structures of tris(methyltrihydroborato)ytterbium(III)etherate and tris(methyltrihydroborato)holmium(III)bis(pyridine) Pages 97-101 Ron Shinomoto, Allan Zalkin, Norman M. Edelstein

Crystal structure of a dysprosium trichloride complex with oxygen donor ligands Pages 103-104 Zhang Xing-Wang, Li Xing-Fu, F. Benetollo, G. Bombieri

Recent advances in the chemistry of UX4 complexes (X=Cl, Br and I) Pages 105-106 J. G. H. Du Preez, B. Zeelie

Ultrasonic relaxation measurements on erbium chloride in water and aqueous methanol Pages 107-109 Herbert B. Silber, Yue Zhang

Possible stabilization of the tetravalent oxidation state of berkelium and californium in acetonitrile with triphenylarsine oxide Pages 111-112 Gerard F. Payne, Joseph R. Peterson

A mössbauer effect study of some europium(III) nitrate complexes with unidentate oxygen-donor ligands Pages 113-117 Fernande Grandjean, Gary J. Long, Margaret L. Buhl, Umberto Russo and, Bruno Zarli, G. Valle

Thermodynamics of Ln(III) complexation with AMP and ATP Pages 119-120 S. M. Shanbhag, G. R. Choppin

Studies on lanthanoid sulfites. Part VII. Preparative and thermal study on rare earth sulfite sulfate hydrates Pages 121-123 Markku Leskelä, J. Everardo X. De Matos, Lauri Niinistö

Thermal decomposition of octakis(p-dimethyl-phenylsulfoxide)lanthanide(III) perchlorates in a helium atmosphere Pages 125-127 M. A. Bañares, M. E. Pérez, R. J. Ruano

Synthesis and characterization of sodium di-μ-hydroxo-bis[3,6-disulpho-1,2-naphthoquinone-1-oximato-O,N-dioxouranate(VI)] Pages 129-130 Anto Vainiotalo, Tuure-Pekka Jauhiainen, Jouko Vepsäläinen, Matti Kauppinen

Synthesis and crystal structure of a complex [perrhenate-bis(1,4-dithiane 1,4-dioxide)mono(μ-1,4-dithiane 1,4-dioxide)triaquaholmium(III) polymer] perrhenate-1,4-dithiane 1,4-dioxide Pages 131-133 J. M. Miranda, M. A. Oliveira, E. E. Castellano, E. Scoralick, L. B. Zinner and, G. Vicentini

Synthesis and characterization of several lanthanide complexes with ethyl α-ketocyclopentyl carboxylate Pages 135-136 M. A. Bañares, A. Angoso, J. L. Manzano, E. Rodríguez, M. T. Blasco

31P and 23Na NMR lanthanide induced shifts in axially symmetric macrocyclic phosphonate complexes Pages 137-139 A. Dean Sherry, C. F. G. C. Geraldes, W. P. Cacheris

Studies on the kinetics of formation and dissociation of the cerium(III)-DOTA complex Pages 141-142 E. Brücher, G. Laurenczy, Z. S. Makra

The formation of mixed complexes of NdMEDTA and NdHyEDTA with acetate Pages 143-145 W. D'olieslager, M. De Jonghe, M. Wevers, L. Heerman

Water exchange kinetics on lanthanide(III) ions: a variable temperature and pressure 17O NMR study Pages 147-149 Cédric Cossy, Lothar Helm, Andre E. Merbach

139La NMR and quantitative FT-IR investigation of the interaction between Ln(III) ions and various anions in organic solvents Pages 151-152 Jean-Claude G. Bünzli, André E. Merbach, Roger M. Nielson

Competitive equilibria in lanthanide trifluoromethanesulfonate solutions in propylene carbonate containing a 15-crown-5 ether Pages 153-154 Francis Pilloud, Jean-Claude G. Bünzli

Synthesis and characterization of complexes of neodymium(III) with piperazines Pages 155-157 Arun Kumar Trikha

Dioxouranium(VI) complexes with γ disulfoxides Pages 159-160 Emelvira B. de Paiva E Saá, Maria Isaura D. Holanda, João Aldésio P. Holanda

Synthesis and infrared studies of dichlorolanthanide complexes of ethyl 2-(diphenyloxophosphino)acetates Pages 161-162 Hsu-Kun Wang, Ming-Jie Zhang, Ji-Tao Wang

Complexation of trivalent lanthanides and yttrium by benzylidenepymvates in aqueous solution Pages 163-164 C. B. Melios, J. T. Souza Campos, M. A. C. Mazzeu, L. L. Campos, M. Molina, J. O. Tognolli

Synthesis and characterization of rare earth monophthalocyanine complexes Pages 165-168 Ni Jiazan, Shi Feng, Li Zhenxiang, Yin Shaoming

Synthesis, structure and reactivity of organometallic complexes of Sm(II) Pages 169-170 William J. Evans

Reactivity of the uranium-carbon σ-bond in ‘silylamido’ compounds Pages 171-176 A. Dormond, A. Aaliti, A. El Bouadili, C. Moise

Small molecule activation at the uranium carbon multiple bond Pages 177-181 John W. Gilje, Roger E. Cramer

Tris(2,6-di-t-butylphenoxo)yttrium: a three-coordinate hydrocarbon-soluble aryloxide of yttrium Pages 183-184 Peter B. Hitchcock, Michael F. Lappert, Richard G. Smith

The synthesis and X-ray structure of a novel monocyclopentadienyluranium(IV) chloride [UCp′''Cl2(THF)(μ-Cl)2Li(THF)2][Cp′''=η-C5H2(SiMe3)3-1,2,4] Pages 185-186 Michael A. Edelman, Michael F. Lappert, Jerry L. Atwood and, Hongming Zhang

Organoactinide complexes. Part I. Synthesis and structure of tris(cyclopentadienyl)uranium fluoroalkoxides Pages 187-188 Friedrich Knösel, Herbert W. Roesky, Frank Edelmann

The reaction of diiodoethane with neptunium and plutonium metals Pages 189-191 D. G. Karraker

Reduced biuranocenylene - a mixed valence organouranium compound. Pages 193-194 Andrew Streitwieser Jr., David C. Eisenberg

Studies on organolanthanide complexes. XVII. Syntheses and identification of 1,1′-pentamethylenedicyclopentadienyl lanthanide chlorides, yttrium chloride and yttrium cyclopentadienyl derivative Pages 195-199 Changtao Qian, Zuowei Xie, Yaozeng Huang

The coordination chemistry of trivalent uranium and cerium Pages 201-202 J. G. Brennan, S. D. Stults, R. A. Andersen, A. Zalkin

Studies on rare earth allyl compounds. IV. The crystal structure of [Li2(μ-C3H5)(C4H8O2)3] [Ce(η3-C3H5)4] Pages 203-207 Zuen Huang, Mingqin Chen, Wenjie Qiu, Wenling Wu

Crystal and molecular structure of a novel Oeganoactinide Complex: [U(C5H5)3(NCCH3)2]+ [Th(C5H5)Cl4(NCCH3)]− Pages 209-210 J. Rebizant, C. Apostolidis, M. R. Spirlet, B. Kanellakopulos

Structural investigations of the isomorphous propionitrile-tris(η5 -cyclopentadienyl) lanthanoid(III) (Ln=La, Pr, Yb) complexes and of the corresponding 1:2 adducts Pages 211-213 M. R. Spirlet, J. Rebizant, C. Apostolidis, B. Kanellakopulos

Structural chemistry of lanthanide dicydopentadienide halides. Part 5. Gadoliniumdicyclopentadienidechloride Gd(C5H5)2Cl]4 Pages 215-217 W. Lamberts, B. Hessner, H. Lueken

The europium(III) ion as spectroscopic probe in bioinorganic chemistry Pages 219-222 Jean-claude G. Bünzli

Spectroscopic properties of tetravalent actinide ions in solids Pages 223-241 J. C. Krupa

Recent developments in the theory of f-element molecules Pages 243-245 Pekka Pyykkö

An MO study on structures and reactivity of organoactinides based on the extended Hückel method: actinide bis(cyclopentadienyl) complexes Pages 247-251 Kazuyuki Tatsumi, Akira Nakamura

Crystal field effects in lutetium disilicates doped with Eu3+ Pages 253-255 Jorma Hölsä, Pierre Porcher, Christian Chateau

Luminescence of Eu3+ ion as a structural probe in high temperature phase transformations in lutetium orthoborates Pages 257-259 Jorma Hölsä

Photoluminescence study of Tb3+ doped alkaline earth sulfide thin films Pages 261-263 Milja Asplund, Jorma Hölsä, Markku Leskelä, Lauri Niinistö, Erja Nykänen

Energy transfer in some luminescent gadolinium fluorides Pages 265-267 R. Mahiou, J. Metin, D. Zambon, A. Arbus, M. T. Fournier, J. C. Cousseins

Optical properties of U4+ in α-ThBr4 Pages 269-271 E. Simoni, S. Hubert, M. Genet

Laser induced fluorescence of 249Bk4+ in CeF4 Pages 273-274 G. M. Jursich, J. V. Beitz, W. T. Carnall, G. L. Goodman, C. W. Williams, L. R. Morss

Crystal-field analysis of Tb3+:LaF3 and Gd3+:LaF3 in C2v site symmetry Pages 275-276 W. T. Carnall, G. L. Goodman, G. M. Jursich, R. S. Rana, P. Vandevelde, L. Fluyt and, C. Görller-Walrand

A spectroscopic study of the TbAl3(BO3)4 crystal Pages 277-279 C. Görller-Walrand, P. Vandevelde, I. Hendrickx, P. Porcher, J. C. Krupa

Absorption and emission analysis of Pr3+ in yttrium aluminium garnet Pages 281-285 E. Antic-Fidancev, M. Lemaître-Blaise, P. Caro, J. C. Krupa

Spin-correlated crystal-field interactions in NdF3, Nd3+:LaF3, and Nd3+:LiYF4 Pages 287-290 C. K. Jayasankar, F. S. Richardson, M. F. Reid, P. Porcher and, P. Caro

Re-examination of the 4f3 energy parameters for several systems with neodymium—oxygen atom coordination Pages 291-294 C. K. Jayasankar, F. S. Richardson, M. F. Reid, P. Porcher and, P. Caro

Two-photon excitation of the Sm2+ ion in BaClF Pages 295-296 J. C. Gâcon, J. M. Marcerou, B. Jacquier

Eu(III) as a sensitive probe of ligand conformation in dicyclohexyl-18-crown-6 complexes Pages 297-298 D. Plancherel

Importance of the ligand excess in investigations of the fluorescence intensity of the lanthanide(III) complexes of aminopolyacetic acids in aqueous solutions Pages 299-300 M. Elbanowski, S. Lis, B. Makowska, J. Konarski

Luminescence behaviour of uranyl nitrate hydrates Pages 301-302 Hugh D. Burrows, Sebastião J. Formosinho, M. Da Graça Miguel

Spectroscopic investigation of Eu-EDTA complexes Pages 303-306 J. Dexpert-Ghys, J. Halwani, B. Piriou

Peculiar fluorescence of Eu3+ in oxyapatites Page 307 B. Piriou, D. Fahmi, J. Dexpert-Ghys, A. Taitai and, J. L. Lacout

The complexation of uranyl ion with carboxylic acids studied by 1H and 13C NMR Pages 309-310 M. Teresa Nunes, Victor M. S. Gil

A NMR study of lanthanide-NOTA chelates as aqueous paramagnetic shift and relaxation probes Pages 311-313 C. F. G. C. Geraldes, M. P. M. Marques, A. D. Sherry

Lanthanum-139 NMR spectroscopy of triscyclopentadienyllanthanum(III) derivatives: a promising new tool for solution studies Pages 315-318 Stefan H. Eggers, Martin Adam, Erhard T. K. Haupt, R. Dieter Fischer

Anisotropy in the proton NMR paramagnetic shift of cyclooctatetraene and cyclopentadiene anions coordinated to U(IV) Pages 319-321 B. R. McGarvey, S. Nagy

A model for describing paramagnetic Mössbauer relaxation spectra of organometallic 237Np compounds Pages 323-325 G. Adrian

Photoelectron spectroscopy (UPS/XPS) study of Np2O3 formation on the surface of neptunium metal Pages 327-329 J. R. Naegele, L. E. Cox, J. W. Ward

A photoelectron study of pentavalent uranium imido complexes Pages 331-333 John G. Brennan, Jennifer C. Green, Catherine M. Redfern

The electronic structure of organometallic complexes of the f elements. XIX. Parametrization of the crystal field splitting patterns of quasi trigonal bi-pyramidal anionic complexes involving the tris(η5-cyclopentadienyl)-uranium(IV) moiety Pages 335-337 Hanns-Dieter Amberger, Hauke Reddmann, George Shalimoff and, Norman M. Edelstein

The electronic structure of organometallic complexes of the f elements.XXI. The crystal field splitting pattern of perdeuterated tris(η5-cyclopentadienyl)-uranium(IV)chloride in the low energy range Page 339 Hanns-Dieter Amberger, Hauke Reddmann, Norman M. Edelstein

Oscillator strengths for f → d transitions in lanthanide and actinide aqua ions Pages 341-342 B. R. Judd

Electronic Raman effect in lanthanide(III) complexes. Ligand polarization contribution Pages 343-344 J. Sztucki, W. Strk

Photostimulated oxygen exchange and photochemical properties of uranyl ions Pages 345-351 S. A. Gaziev, N. G. Gorshkov, L. G. Mashirov, D. N. Suglobov

New 166Er nuclear states populated in the 166mHo decay Pages 353-354 Th. Ogandaga, J. Dalmasso, A. Hachem, G. Ardosson